Process Intensification in Practice: Ethylene Glycol Case Study, Chemical Industry & Chemical Engineering Quarterly, 2011 International Symposium on Advanced Control of Industrial Processes (ADCONIP), View 3 excerpts, cites methods and background, By clicking accept or continuing to use the site, you agree to the terms outlined in our. Roelof L. J. Coetzer, J. Pirow Engelbrecht, J. Christo Crause and Dennis K. J. Lin. 1981; 174:383–404. Martino Di Serio,, Riccardo Tesser, and. Chemical Engineering and Processing: Process Intensification. E. Santacesaria, R. Tesser, M. Di Serio. Microwave-assisted polyol synthesis of copper nanocrystals without using additional protective agents. T. Biegler, Maria P. Ochoa, Logan Matthews, Jeff Ferrio, John Weston, Nima Nikbin. Use the link below to share a full-text version of this article with your friends and colleagues. I. Carcinogenicity of ethylene oxide in comparison with 1,2-propylene oxide after subcutaneous administration in mice. Industrial & Engineering Chemistry Research. Thus the…, Kinetics of esterification of acetic acid with 1-octanol in the presence of Amberlyst 36, Thermal reactivity of ethylene oxide in contact with contaminants: A review, Investigation of reaction parameters, kinetics and mechanism of oleic acid esterification with methanol by using Amberlyst 46 as a catalyst, Research on industrial modeling of ethylene oxide hydration reactor, Design and analysis of an intensified column with side reactor configuration for ethylene glycol production from ethylene oxide, Synthesis of ethylene glycol and terephthalic acid from biomass for producing PET, Simulation and Analysis of a Reactive Distillation Column for Removal of Water from Ethanol–Water Mixtures, The preparation and catalytic performance of graphene-reinforced ion-exchange resins. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Amberjet 4200/HCO3− was used as the heterogeneous catalyst, which was found to be the most effective among the four types of cross-linked styrene−divinylbenzene anion-exchange resins tested. The production of ethylene oxide accounts for approximately 11% of worldwide ethylene demand. Bhajendra N. Barman, Donald H. Champion, Stephen L. Sjoberg. The latter data was incorporated into a reaction model useful for the determination of ethylene oxide storage stability and pressure relief system design under water‐contamination scenarios. Kinetic data on the hydration of ethylene oxide was obtained from both uncatalyzed and heterogeneously catalyzed reactions using a pressurized batch reactor. Learn more. B. Box 1380, Houston, TX 77251. The chlorohydrin process was unattractive for several reasons, including low efficiency and loss of valuable chlorine into calcium chloride. Please reconnect. * Corresponding authors a Chemistry Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia E-mail: mnahid@kfupm.edu.sa Tel: +96613860 2529 b Laboratory of Polymer and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Your Mendeley pairing has expired. Reactivity of ethylene oxide in contact with basic contaminants. Independent experimental runs have been performed to evaluate densities of any possible reaction mixture and the corresponding ethylene and propylene oxide solubilities. In the present paper the kinetics of ethoxylation and of propoxylation of ethylene glycol catalyzed by KOH have been studied. Zentralbl. Ethylene oxide is one of the most important intermediates in the chemical industry, being used for reactions with ethylene, water, alcohols and organic acids. If you do not receive an email within 10 minutes, your email address may not be registered, View the notice. and you may need to create a new Wiley Online Library account. Semantic Scholar is a free, AI-powered research tool for scientific literature, based at the Allen Institute for AI. Find more information on the Altmetric Attention Score and how the score is calculated. Hyg. Kinetic data on the hydration of ethylene oxide was obtained from both uncatalyzed and heterogeneously catalyzed reactions using a pressurized batch reactor. Modification of zeolite L (LTL) morphology using diols, (OH)2(CH2)2n+2On (n=0, 1, and 2). A kinetic model has been developed for taking into account this peculiar behavior and the corresponding kinetic parameters have been determined. Commercial production of ethylene oxide dates back to 1914 when BASF built the first factory which used the chlorohydrin process (reaction of ethylene chlorohydrin with calcium hydroxide). Amberjet 4200/HCO3− was used as the heterogeneous catalyst, which was found to be the most effective among the four types of cross-linked styrene−divinylbenzene anion-exchange resins tested. Thermal reactivity of ethylene oxide in contact with contaminants: A review. Journal of Thermal Analysis and Calorimetry. Philipp Schrader, Christian Paasche, Sabine Enders.

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